• 专利附录
  • 专利说明
  • 权利要求
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  • 同族专利
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    • 专利摘要:
    Use of electrolysis water having a neutral to basic pH, which is prepared in a single-cell electrolysis cell (1) having at least one diamond electrode (7) from an aqueous saline solution, on plants for preventing or inhibiting it. Reduce spore germination and mycelial growth of fungi of the genera Botrytis and Fusarium.
    公开号:AT514092A1
    申请号:T50115/2013
    申请日:2013-02-21
    公开日:2014-10-15
    发明作者:
    申请人:Pro Aqua Diamantelektroden Produktion Gmbh & Co Kg；
    IPC主号:
    专利说明:

    PA 8338
    per aqua diamond electrodes production GmbH & Co KG
    Use of electrolysis water and methods for preventing or obstructing 5 and for reducing spore germination and mycelium growth of fungi of the genera Botrytis and Fusarium
    Description 10 The invention relates to the use of electrolysis water and a method for the
    Preventing or obstructing and reducing spore germination and mycelium growth of fungi of the genera Botrytis and Fusarium,
    It is known that electrolysis water has a cleaning and disinfecting effect 15. According to the prior art, electrolysis water is produced from a salt solution, usually a sodium chloride solution, in an electrolytic cell in which the anode and cathode are made of conventional materials and separated by a non-selective membrane. Electrolysis of the NaCl molecules produces low pH, high redox potential electrolyzed water in the anode chamber and higher pH and lower redox potential electrolytic water in the cathode chamber. Due to the disinfecting effect of chlorine and oxygen, which are split off during the electrolysis, a germ killing is achieved. A number of published studies are concerned with the use of electrolysis water for the treatment of phytopathogenic fungi, the published studies referring to electrolyzed water with an acidic pFe value or to neutral electrolysis water. The publication Guentzel JL, Lam KL, Callan MA, Emmons SA, Dunham VE (2010): Postharvest management of gray and brown on surfaces of peaches and grapes using electrolyzed oxidizing water, International Journal of Food Microbiology 143, 54-60 For example, with the use of nearly neutral, a pH of 6.3-30 to 6.5 having Elektrolysewasser for inactivation of Botrytis cinerea on the surface of fruits. The publication Buck JW, I he MW, Oetting RD, Hung YC (2002): In vitro fungicidal activity of acidic electrolyzed oxidizing water, Plant Disease 86, 2/29 2 278-281, deals with the use of acid electrolysis water for elimination of Botrytis cinerea.
    WO 2008/101364 A2 discloses a crop protection method for controlling 5 plant pests by means of electrolytically produced oxidative radicals, UV-C light and air-assisted electrostatic spray technology. The production of biocidal oxidative radicals takes place in aqueous, saline solutions by means of electrolysis, wherein in one of the electrolysis methods described here, a special electrolytic cell is used with diamond-coated electrodes, wherein a cocktail of oxidative radicals 10 near the neutral range with a pH of 6.4 to 6,8 is created.
    The subject matter of various studies forming and the known from the patent literature process have apparently not been suitable to be used in crop protection 15 preventively against and for controlling infestation by phytopathogenic fungi effectively and, above all, economically. Decisive for this is likely that in the conventional electrolysis in a two-chamber electrolysis cell quasi half of the electrolysis water formed must be discarded and that the electrolysis water used did not have the required effectiveness. 20
    Mushrooms of the genera Botrytis and Fusarium are among the most significant plant pests worldwide, fungi of the genus; Fusarium are, for example, the causative agent of cereal fusariosis and maize stalk lice. The fungi belonging to the genus Botrytis are also important plant pests that cause rot. The economic damage caused by the fungi of the genera Botrytis and Fusarium is enormous. Combating Botrytis and Fusarium is usually difficult and expensive. For example, in viticulture a combination of viticultural techniques, such as defoliation immediately after flowering, is common with botrytic spraying. If rape is attacked by Botrytis cinerea, the use of fungicides is no longer effective. The Fusarium control with fungicides in cereals is a barely solved problem,
    Partial success can be achieved with drugs such as prothioconacol and tebuanazole, where 3/29 3
    Visible infestation can no longer be combated, so that elaborate preventive measures are necessary.
    The invention is therefore an object of the invention to provide a means for effective prevention, 5 suppression or reduction of spore germination and mycelium growth of the phytopathogenic fungus species Botrytis and Fusarium on plants and fruits available, this means enable economic use on a broad basis and its Application in humans should be harmless to health. 10
    The object is achieved according to the invention by the use of electrolysis water with neutral to basic pH, which is prepared in a einkammrigen electrolysis cell, which has at least one diamond electrode, from an aqueous salt solution, on plants or fruits to prevent or obstruct 15 or reducing Spore germination and mycelial growth of fungi of the genera
    Botrytis and Fusarium.
    The inventive method is characterized in that the plants or the fruits are treated with an electrolysis water, which is prepared in a einkammrigen 20 electrolysis cell having at least one diamond electrode, from an aqueous salt solution and has a neutral to basic pH.
    According to the invention, electrolysis water is used, which has a pH in the basic range and contains a very broader spectrum of oxidizing agents. During the electrolysis of the aqueous salt solution in a single - chamber electrolysis cell, the pH of the solution increases due to the consumption of chlorides in the anodic chlorine production. Because no separation of anode and cathode space is provided, mixing and neutralization of acidic anolyte with alkaline catholyte takes place directly, so that, according to the invention, a neutral to basic electrolyte water containing at the same time various oxidizing agents is prepared. One reason for the surprisingly good effectiveness of the invention. In particular basic electrolysis water in comparison with acidic water of pyrolysis should be in an interaction of the basic components of the solution with the spore wall of the fungal spores. Spores, which are currently in a physiologically inactive phase, have due to their hydrophobic spore wall some protection against 5 Oxidationsmittelangriffen, so that with simple oxidants mycelium and sprouting spores just can be damaged. By the alkaline solution, however, the spore wall becomes more hydrophilic and permeable, which also allows the oxidizing agents in the electrolysis water to penetrate into spores which are physiologically not active. 10
    Basically, it is known from the prior art that by electrolysis at low pH larger amounts of oxidizing agents can be produced. This is due to the fact that at low pH values, a low concentration of OH ions in the water is available, whereby the anodic oxygen production 15 (= unwanted competing reaction) over the oxi-on-d compound production (e.g.
    Chlorine production from chloride) is pushed back. Therefore, the electrolytic waters known in the prior art are virtually all acidic. By using diamond electrodes with a high overvoltage compared to the oxygen production as property of the electrode itself, despite high OH concentrations in the electrolyte or at the anode, also at higher pH values, oxidants with high potential are produced in good yield. The competitive reaction of oxygen production does not have to be suppressed by the pH value here. Therefore, with the arrangement according to the invention, the better-acting alkaline oxidizing agents can be directly produced and applied with good efficiency for the first time
    The use of the electrolysis water has enormous potential, since the ancients of the genera Botrytis and Fusarium in garden, field and orchard annually cause serious economic damage. The electrolysis water can prevent the use of synthetic fungicides at a time when more emphasis is placed on environmental sustainability and product sustainability. The electrolysis water shows a high activity against fungi of the genera Botrytis and Fusarium, but hardly 5/29: 5 toxic effects on the plants themselves and on the environment. One of the main advantages of electrolysis water is therefore its safety, it comes with organic material in contact, it is back to ordinary water. According to the invention, the electrolysis water on the one hand for the prophylactic treatment of plants, parts of plants and fruits and on the other hand already infected by Botrytis or Fusarium plants, parts of plants and fruits. A particularly good effect shows electrolysis, which has a pH between 7.1 and 11.5, in particular between 7.1 and 9.5. 10
    Electrolysis water having an otimal concentration of oxidizing agent with a good efficiency can be produced in particular in an electrolysis cell which contains at least one bipolar, in particular boron-doped, diamond electrode. Additionally or alternatively, the electrolysis cell can advantageously contain at least one contact electrode which contains a metal electrode, whether it be a conventionally designed diamond electrode or else a diamond particle electrode.
    The basic solution from which the electrolysis water is produced in the electrolysis cell can be produced in a very simple manner. Particularly suitable as a base solution is a 20 aqueous NaCl, KCl or MgCE solution, wherein NaCl, KCl or MgCU can also be used in any combination with one another for the preparation of the base solution. In particular, 2 g to 8 g of NaCl, KCl and / or MgCE are dissolved in 1 L of water.
    Particularly effective and advantageous is the use of the electrolysis water on plants, parts of plants or fruits for preventing or obstructing
    Spore germination as well as the destruction of already formed mycelium of the fungus species Botyrtis cinerea and Fusarium culmorum. These two species of fungus cause enormous economic damage to crops and fruits worldwide. 6/29 6
    For the application of the electrolysis water this can be sprayed on the plants in question, on parts of plants or on F rüchte or the plants, plant parts and fruits can also be washed with the electrolysis water. 5 The treatment of plants, parts of plants and fruits can then be grown in the field, for example, directly in a field, möglich.Möglich and very advantageous, however, is the treatment of plants, plant parts and fruits already harvested, before and during their transport and their storage and even in the shop. In addition to the proven effectiveness of the electrolysis water, it is also of great advantage in these 10 applications that the oxidative constituents of the electrolysis water self-degrade after a relatively short time.
    Further features, advantages and details of the invention will now be explained in more detail with reference to the drawing. 15 show
    Fig.l is a schematic sketch of an Aüsfuhrungsform an electrolytic cell for generating electrolyte sewasser and
    Fig. 2a, 2b and 3 to Fig. 7 are diagrams showing the effect of the electrolysis water on 20 representatives of the fungus species Botrytis and Fusarium.
    Within the scope of the invention, single-cell electrolysis cells which contain at least one diamond electrode can be used to produce electrolysis water. The term "diamond electrode" covers all diamond electrodes produced by known processes, for example the 25 CVD process, and also di-ant-electrode electrodes. The electrolysis cell may be designed such that at least one of the contacting electrodes, preferably the anode, is a diamond electrode, and / or that at least one bipolar diamond electrode is installed in addition to the contacting electrodes. As a bipolar diamond electrode is especially a 30 Di amantpartikel el electrode. 7/29 7
    FIG. 1 shows an embodiment of an electrolytic cell 1 which can be used within the scope of the invention for the production of electrolysis water. The electrolytic cell 1 has a chamber 2 through which water can pass, which has at least one inlet opening 3 and at least one outlet opening 4. The electrolysis cell 1 5 further comprises in a known manner two in the chamber 2 wall-mounted Kontaktieaingselektroden, a cathode 5 and an anode 6. In the chamber 2 is in parallel arrangement to the contacting electrodes 5, 6 at least one bipolar Di on antp arti elector el ode 7 positioned, wherein in the illustrated Ausfuhrungsforffi in the electrolysis cell 1, two bipolar diamond particle electrodes 7 are included. Each 10 bipolar diamond particle electrode 7 preferably has boron-doped, synthetically produced diamond particles which are embedded in one layer in a carrier layer of electrically insulating material, for example glass, ceramic or a plastic, the diamond particles being deposited on both sides of the carrier layer. Such diamond particle electrodes can be produced, for example, according to the method described in the 15 Austrian patent Mir, 503 402.
    The two contacting electrodes 5, 6 may be commercially available electrodes, in particular of iridium / ruthenium or platinum-coated titanium sheet, graphite electrodes or conventional diamond electrodes 20 produced, for example, according to the CVD method. At least one of the contacting electrodes 5, 6 can also be a
    Diamond particle electrode, which has been provided on one side with a contacting layer.
    In order to produce the electrolysis water, the electrolytic cell 1 is supplied with water at the inflow opening 3 25 in which NaCl, KCl or MgCE has been dissolved. For the preparation of the salt solution, between 2 g and 8 g of NaCl, KCl or MgCf, also in combination, are dissolved in 1 l of normal tap water or water pretreated in 1 l, for example softened water. The amount added depends on the desired concentration of oxidative radicals or oxidizing agents in the electrolysis water formed, whereby the sum of electrode surfaces in the electrolysis cell 1 and the charge of charge (Ah / E) also influence the concentration. These parameters are coordinated with one another 8 / 29 8 or that, in particular, between SO mg / L and 200 mg / L of oxidizing agent, measured as sum parameter free chlorine, are contained in the electrolysis water. The electrolyzed water is formed from the saline solution that can be provided in advance as needed and in situ. This measure allows the use of flow cells for the production of 5 electrolysis directly and directly on site, for example by incorporating one or more Kleolytys cell (s) 1 in a conventional sprayer, which can be designed as a larger sprayer or I landsprühgerät. The spraying device and its other components are not the subject of the invention, therefore not described separately and can be executed according to the state of the art.
    The electrolysis water formed, which leaves the electrolysis cell 1 at the at least one outflow opening 4, is pumped in a known manner through the spraying device to at least one spray nozzle and applied to the plants to be treated. The electrolysis water formed in an electrolytic cell 1 is neutral to basic and in particular has a pH of between 7.1 and 11.5, preferably between 7.1 and 9.5. As explained in the introduction, this is one of the reasons why the electrolysis water according to the invention inhibits particularly well the spore germination and the mycelium of phytopathogenic fungi of the genera Botrytis and Fusarium compared to electrolysis water which is produced in conventional electrolysis cells. The broad spectrum of oxidizing agents, such as free chlorine, HOCl, OCF ions, H 2 O 2 (hydrogen peroxide) and ozone, are also responsible for the action of the electrolysis water. The electrolysis water produced in a single-chamber electrolysis cell 1 containing at least one diamond electrode is particularly effective to prevent and hinder spore germination and destruction of mycelium all phytopathogenic fungi of the genera Fusarium and Botrytis, Fusaria are among the most important harmful fungi in cereals and maize and other crops worldwide. The electrolysis water 30 can be used against all Fusarium species, in particular Fusarium avenaceum, Fusarium chlamydosporum, Fusarium coeruleum, Fusarium dimerum, Fusarium 9/29 9 incamatum, Fusarium moniliforme, Fusarium napiforme, Fusarium oxysporum, Fusarium poae, Fusarium proliferatum, Fusarium sacehari, Fusarium solani , Fusarium sporotrichioides, Füsäriüm subglutinans, Fusarium tabacinum and Fusarium verticillioides and their hybrids, The fungus Fusarium culmorum applies among other Fusarium species 5 as the cause of ÄhrenfuSäriOSe on cereals and stalk rot on corn. The fungus causes enormous economic damage worldwide in grain and corn growing areas. An important aspect of the degradation of plants by Fusarium culmorum is the production of toxins that make the affected crop unsuitable for human and animal nutrition. The fungi belonging to the genus Botrytis are also 10 major plant pests, they live as parasites and cause rot. Botrytis endangers humans mainly through its high allergenic potential. The electrolysis water is suitable for use against botrytis cinerea, botrytis fabae, botrytis calthae, botrytis ranuncuh, botrytis ficariarum, botrytis pelargonii, botrytis paeoniae, botrytis hyacinthi, botrytis tulipae, botrytis elliptica, botrytis squamosa, botrytis aclada, botrytis x allii, 15 botrytis byssoidea , Botrytis globosa, Botrytis porri, Botrytis sphaerosperma, Botrytis narCissolao, Botrytis polyblastis, Botrytis galanthina, Botrytis convoluta, Botrytis croci and Botrytis gladiolorum and their hybrids. The fungus Botrytis cinerea is the causative agent of gray mold blight and due to the high yield and quality losses caused by it and the wide host plant circle has a great economic importance. Numerous host plants, such as strawberries, grapevine, salads, I limberries, tomatoes, oilseed rape, cabbage, hops and the like, can be affected.
    The electrolysis water can be applied to all components or only individual components of plants and fruits. Plants, plant parts and fruits can be sprayed or washed with the electrolysis water. The electrolysis water can be used preventively or in case of infestation, furthermore once or at certain intervals. It is also possible to treat plants, parts of plants or fruits before or during transport, storage or prophylactically at the point of sale. 30 With the two particularly economically relevant fungus species Fusarium culmorum and
    Botrytis cinerea were bioessays based on spore germination and mycelial development in 10/29 10
    Liquid media established and tested in the laboratory. For the experiments, Fusarium culmorum isolate (IFA 301, provided by M. Lemmens, IFA Tulln) and Botrytis cinerea isolated from an affected Melanzani were used. For the production of the spore suspensions, the fungi were cultured under standardized conditions for several weeks on a nutrient medium, coated under sterile conditions with autoclaved, distilled water and then set the desired spore concentration using a Thoma counting chamber exactly. For the production; of the electrolysis water, on the one hand two NaCl solutions, 10 NaCl (1) and NaCl (2), and on the other hand two solutions of NaHCo ,, NaiSCL and MgSOt, NNM (1) and NNM (2) were used. For the NaCl solutions NaCl (1) and NaCl (2), 5 grams of 99.9% NaCl (C. Roth, Karlsruhe) were dissolved in 1 L of distilled water and then in an electrolytic cell with 15 iridium / ruthenium electrodes as contacting electrodes and treated with three boron-doped, bipolar diamond particle electrodes (company per aqua diamond electrodes production GmbH), so that the concentration of oxidizing agent in the electrolysis water was about 300 mg / L. The pH of both electrolyzed waters was 9.5. 20 For comparison purposes, a sodium chloride solution 1 was prepared which was not in the
    Electrolysis cell was treated. For the solutions NNM (1) and NNM (2), a total of 2.72 g of a mixture of NallCXE, NaiSiL and MgSO-t (each C. Roth) were dissolved in 1 L of distilled water. Also in this case, two different Hlektrolysewasser were prepared by different parameters, NNM (l) with a pH of 8.7 and NNM (2) with a pl I-Werl of 9.0.
    An untreated NNM solution served as a reference solution. 30 The influence of electrolysis water on mycelial growth and spore germination has been reported in
    Microtiter plate tests. For this purpose, 200 μl of spore suspension (107 ml / 1 11/29 11
    Spores in Botrytis, 106 ml.'1 spores in Fusarium) with 1800 pL of electrolysis water, the NaCl solution, or a reference solution (distilled water) mixed in test tubes. The effect of the solutions was stopped by adding a neutralizing buffer solution (pH 7.2) or by adding distilled water. These plates 5 were then incubated at 24 ° C. After 24 h, any spore germination was stopped by means of 10 μl / well of lactophenol blue and the number of germinated spores was determined microscopically. Each experiment was repeated three times. For mycelial growth, the microtiter plates were loaded as described above and the optical density was measured with a microplate reader (FluoStar Omega) at 600 nm after 0 h, 24 h, 48 h, 72 h and 96 h. The statistical evaluation was carried out using ΑΝΟΜΑ and Kruskal Wallis Test, with Stätgraphics 16 and SPSS. The graphical representation of the results was done with Sigma Plot 12. 15 As shown in Figures 2a and 2b, Botrytis cinerea showed a statistically significant reduction in spore germination in those spore suspensions treated with NaCl (1) and NaCl (2) , For NNM (l) and NNM (2), however, no statistically significant differences were observed with the electrolysis solutions not treated in the electrolysis cell. 20
    The spore germ tests with Fusarium culmorum (Figure 3) show that treatments with NaCl (1) and NaCl (2) also resulted in a statistically significant reduction in spore germination. For all treatments with NNM (l) and NNM (2) electrolytic solution and electrolysis water scarcely spores were found in the microtiter plates at the evaluation date (data not shown). The treatment may have caused spores to burst in this case.
    The electrolysis NaCl-based water also led to a clear inhibition of mycelial development in Botrytis cinerea. NaCl (2) had a stronger effect than NaCl (I) even for a shorter treatment time, as can be seen from FIG. 4. The
    Mycelium growth is shown over the course of time from 0 to 96 h. For the statistical 12/29 12
    Evaluation of mycelial growth was based on the value of the last measurement (96 h).
    For NNM (2), electrolysis water 240, with a treatment time of 4 min 5, could achieve a statistically significant difference from the other variants (FIG. 5). The other treatments for NNM (l) and NNM (2) did not show statistically significant differences.
    Fusarium culmorum was comparable to Botrytis cinerea in terms of the efficacy of various electrolysis waters. While clear and statistically significantly different values exist for NaCl (I) and NaCl (2) (FIG. 6), this is not equally possible with NNM (1) and NNM (2). In contrast to the results of spore germination, in mycelial growth both electrolysis waters NNM (1) and NNM (2), when treated with NNM (2) for at least 120 s or NNM (1) for 240 s, are significantly different from the others Treatments have (see Fig. 7).
    The experiments substantiate and permit the conclusion that electrolysis water, which according to the invention is produced in an electrolytic cell having at least one diamond electrode and has a basic pH, has a very good activity against the other phytopathogenic fungi of the genera Botrytis and Fusarium. This results in numerous potential applications for this electrolysis water in agriculture and horticulture. 13/29 5 13
    Reference number 1 ....................... Electrolytic cell 2 ....................... Chamber 3 ....................... Inflow 4 ....................... Drain hole 10 5 ....................... Cathode 6 ...................... .Anode 7 ....................... diamond particle electrode 14/29
    权利要求:
    Claims (19)
    [1]
    1. The use of electrolysis water with neutral to basic pH, which in a single-chamber electrolysis cell (1), which has at least one diamond electrode (7), is produced from an aqueous salt solution on plants or fruits to prevent or obstruct or reduce of spore germination and mycelial growth of fungi of the genera Botrytis and Fusarium. 10
    [2]
    2. Use of 1'lektrolysewasser according to claim 1 for the treatment of Botrytis cinerea. Use of electrolysis water according to claim 1 for the treatment of Fusarium culmorum.
    [3]
    4. Use of electrolysis water according to one of claims 1 to 3 with a pH between 7.1 and 11.5, in particular between 7.1 and 9.5.
    [4]
    5. Use of electrolysis water according to any one of claims 1 to 4, which is prepared in an electrolytic cell containing at least one bipolar, in particular boron-doped, Di on antparti eld elecrode (7). Use of electrolytic water according to one of Claims 1 to 5, which is produced in an electrolysis cell which contains at least one diamond electrode as the contact electrode.
    [5]
    7. Use of electrolysis water according to one of claims 1 to 6, prepared from an aqueous NaCl, KCl or VlgCE solution. 15/29 30 15
    [6]
    8. Use of Hlektrolysewasser according to claim 7, prepared from a salt solution, which was added between 2 g and 8 g NaCl and / or KCl and / or MgCl 2 in 1 L of water.
    [7]
    9. Use of Hlektrolysewasser according to any one of claims I to 8 as a spray for spraying on plants, plant parts or fruits.
    [8]
    10. Use of electrolytic water according to any one of claims 1 to 9 for washing plants, parts of plants or fruits. 10
    [9]
    11. The use of electrolysis water according to any one of claims 1 to 10 for the treatment of plants, parts of plants barren fruits in the region, the harvested plants or fruits, also for the treatment of plants or fruits before or during their transport, storage or in the shop. 15
    [10]
    12. A method for preventing or obstructing or reducing spore germination and mycelium growth of fungi of the genera Botrytis or Fusarium on plants or fruits, characterized in that the plants or fruits are treated with an electrolytic water which is used in a single-chamber electrolysis cell ( 1) comprising at least one diamond electrode (7), prepared from an aqueous salt solution and having a neutral to basic pH.
    [11]
    13. The method according to claim 12, characterized in that the electrolysis water has a pH between 7.1 and 11.5, in particular between 7.1 and 9.5.
    [12]
    14. The method according to claim 12 or 13, characterized in that the Elektrölysewasser is prepared in an electrolytic cell, which contains at least one 30 bipolar, in particular boron-doped, Di on antparti eld kel el (7). 16/29
    [13]
    15. The method according to any one of claims 12 to 14, characterized in that the electrolysis water is prepared in an electrolysis cell, which contains at least one diamond electrode as Kontäktierülektlsekt.
    [14]
    16, Method according to one of claims 12 to 15, characterized in that the electrolysis water is prepared by electrolysis of an aqueous solution of NaCl, KCl or MgCla.
    [15]
    17, Process according to claim 16, characterized in that the salt solution by addition of 2 g to 8 g of NaCl and / or KCl and / or MgCl in 1 L of water is produced.
    [16]
    18. The method according to any one of claims 12 to 17, characterized in that the electrolyzed water for preventing or for reducing spore germination and mycelial growth of the fungi Botrytis cinerea and Fusarium culmorum used
    [17]
    19, Method according to one of claims 12 to 18, characterized in that the electrolysis water is sprayed on the plants or their file or on the fruits.
    [18]
    20, Method according to one of claims 12 to 18, characterized in that the plants or their parts or fruits are washed with the electrolysis water.
    [19]
    21, The method according to any one of claims 12 to 20, characterized in that the plants, parts of the plants or the fruits in their cultivation area, in the harvested state, further treated before or during their transport, storage or in the shop with the electrolysis water.
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    CN105624726A|2015-12-30|2016-06-01|金刚宝石水高科技有限公司|Electrode for electrochemical battery|
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    EP3771693A1|2019-07-30|2021-02-03|Lift Holding GmbH|Water disinfection|
    法律状态:
    2018-10-15| MM01| Lapse because of not paying annual fees|Effective date: 20180221 |
    优先权:
    申请号 | 申请日 | 专利标题
    ATA50115/2013A|AT514092B1|2013-02-21|2013-02-21|Use of electrolysis water and methods for preventing or obstructing as well as for reducing spore germination and mycelial growth of fungi of the genera Botrytis and Fusarium|ATA50115/2013A| AT514092B1|2013-02-21|2013-02-21|Use of electrolysis water and methods for preventing or obstructing as well as for reducing spore germination and mycelial growth of fungi of the genera Botrytis and Fusarium|
    EP14155705.8A| EP2769619B1|2013-02-21|2014-02-19|Use of oxidising agents containing electrolysis water and method for avoiding, preventing or reducing spore germination and mycelium growth of fungi of the species botrytis and fusarium|
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